Write chemical reactions to affect the following transformations:
$(i)$ Butan$-1-$ol to butanoic acid
$(ii)$ Benzyl alcohol to phenylethanoic acid
$(iii)$ $3-$Nitrobromobenzene to $3-$nitrobenzoic acid
$(iv)$ $4-$Methylacetophenone to benzene$-1,4-$dicarboxylic acid
$(v)$ Cyclohexene to hexane$-1,6-$dioic acid
$(vi)$ Butanal to butanoic acid.

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(A) $(i)$ $CH_3CH_2CH_2CH_2OH \xrightarrow{CrO_3 - H_2SO_4 (Jones \ reagent)} CH_3CH_2CH_2COOH$
$(ii)$ $C_6H_5CH_2OH$ $\xrightarrow{HBr} C_6H_5CH_2Br$ $\xrightarrow{KCN} C_6H_5CH_2CN$ $\xrightarrow{H_3O^{+}, \Delta} C_6H_5CH_2COOH$
$(iii)$ $C_6H_4(NO_2)Br$ $\xrightarrow{Mg, \text{ether}} C_6H_4(NO_2)MgBr$ $\xrightarrow{CO_2} C_6H_4(NO_2)COOMgBr$ $\xrightarrow{H_3O^{+}} C_6H_4(NO_2)COOH$
$(iv)$ $CH_3-C_6H_4-COCH_3$ $\xrightarrow{KMnO_4/KOH} KOOC-C_6H_4-COOK$ $\xrightarrow{dil. H_2SO_4} HOOC-C_6H_4-COOH$
$(v)$ $C_6H_{10} \xrightarrow{KMnO_4-H_2SO_4, \Delta} HOOC-(CH_2)_4-COOH$
$(vi)$ $CH_3CH_2CH_2CHO \xrightarrow{[O] \text{ or } \text{Tollens' reagent}} CH_3CH_2CH_2COOH$

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Consider the following reaction scheme and choose the correct option for the major products $Q$,$R$ and $S$.

Match the following.
List-$I$ (Substance)List-$II$ (Use)
$(A)$ Methanoic acid$(i)$ Textile
$(B)$ Ethanoic acid$(iv)$ Vinegar
$(C)$ Hexanedioic acid$(ii)$ Polymer
$(D)$ Sodium benzoate$(iii)$ Food preservative

Match the compounds given in Column-$I$ with their names in Column-$II$.
Column-$I$ (Formula)Column-$II$ (Name)
$(A)$ $CH_3-CH=CHCHO$$(i)$ $1,3$-diphenylprop-$2$-en-$1$-one
$(B)$ $CH_3-C(CH_3)=CH-COCH_3$(ii) Acetophenone-$2,4$-dinitrophenylhydrazone
$(C)$ $C_6H_5-CH=CH-COC_6H_5$(iii) But-$2$-enal
$(D)$ $C_6H_5-C(CH_3)=N-NH-C_6H_3(NO_2)_2$(iv) $4$-methylpent-$3$-en-$2$-one

The major product in the following reaction is

In the reaction $Ph-COOH + NaHC^*O_3 \to \text{Product}$,the labeled carbon $C^*$ is found in which of the following products?

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