Write down the $IUPAC$ name for each of the following complexes and indicate the oxidation state,electronic configuration,and coordination number. Also,give the stereochemistry and magnetic moment of the complex:
$(i)$ $K[Cr(H_2O)_2(C_2O_4)_2] \cdot 3H_2O$
$(ii)$ $[Co(NH_3)_5Cl]Cl_2$
$(iii)$ $CrCl_3(py)_3$
$(iv)$ $Cs[FeCl_4]$
$(v)$ $K_4[Mn(CN)_6]$

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(N/A) $(i)$ Potassium diaquadioxalatochromate$(III)$ trihydrate.
Oxidation state of $Cr = +3$.
Electronic configuration: $3d^3 (t_{2g}^3)$.
Coordination number $= 6$.
Shape: Octahedral. Stereochemistry: Shows cis-trans isomerism.
Magnetic moment,$\mu = \sqrt{3(3+2)} = \sqrt{15} \approx 3.87 \ BM$.
$(ii)$ Pentaamminechloridocobalt$(III)$ chloride.
Oxidation state of $Co = +3$.
Electronic configuration: $3d^6 (t_{2g}^6)$.
Coordination number $= 6$.
Shape: Octahedral. Stereochemistry: Shows geometrical isomerism.
Magnetic moment,$\mu = 0 \ BM$ (diamagnetic).
$(iii)$ Trichloridotripyridinechromium$(III)$.
Oxidation state of $Cr = +3$.
Electronic configuration: $3d^3 (t_{2g}^3)$.
Coordination number $= 6$.
Shape: Octahedral. Stereochemistry: Shows facial $(fac)$ and meridional $(mer)$ isomerism.
Magnetic moment,$\mu = \sqrt{3(3+2)} = \sqrt{15} \approx 3.87 \ BM$.
$(iv)$ Caesium tetrachloroferrate$(III)$.
Oxidation state of $Fe = +3$.
Electronic configuration: $3d^5 (e_g^2 t_{2g}^3)$.
Coordination number $= 4$.
Shape: Tetrahedral. Stereochemistry: Optically inactive.
Magnetic moment,$\mu = \sqrt{5(5+2)} = \sqrt{35} \approx 5.92 \ BM$.
$(v)$ Potassium hexacyanomanganate$(II)$.
Oxidation state of $Mn = +2$.
Electronic configuration: $3d^5 (t_{2g}^5)$.
Coordination number $= 6$.
Shape: Octahedral. Stereochemistry: Optically inactive.
Magnetic moment,$\mu = \sqrt{1(1+2)} = \sqrt{3} \approx 1.73 \ BM$.

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Given below are two statements:
Statement $I$ : Dimethyl glyoxime forms a six-membered covalent chelate when treated with $NiCl_2$ solution in presence of $NH_4OH$.
Statement $II$ : Prussian blue precipitate contains iron both in $(+2)$ and $(+3)$ oxidation states.
In the light of the above statements,choose the most appropriate answer from the options given below:

Choose the correct statement$(s)$ among the following:
$(A)$ $[FeCl_4]^-$ has tetrahedral geometry.
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$(C)$ $[FeCl_4]^-$ has higher spin-only magnetic moment than $[Co(en)(NH_3)_2Cl_2]^+$.
$(D)$ The cobalt ion in $[Co(en)(NH_3)_2Cl_2]^+$ has $sp^3d^2$ hybridization.

The volume (in $mL$) of $0.1 \ M$ $AgNO_3$ required for complete precipitation of chloride ions present in $30 \ mL$ of $0.01 \ M$ solution of $[Cr(H_2O)_5Cl]Cl_2$, as silver chloride is close to

$CuSO_{4(aq)}$ $\xrightarrow{H_2S \uparrow} M \downarrow$ $\xrightarrow[\text{Excess}]{KCN} N + O$
Then final products $N$ and $O$ are respectively.

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Total number of molecules/species from the following which will be paramagnetic is $........$
$O_2, O_2^{+}, O_2^{-}, NO, NO_2, CO, K_2[NiCl_4], [Co(NH_3)_6]Cl_3, K_2[Ni(CN)_4]$

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