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Kinetic molecular theory of gases and Molecular collisions Questions in English

Class 11 Chemistry · States of Matter · Kinetic molecular theory of gases and Molecular collisions

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151
DifficultMCQ
Which of the following statement$(s)$ is/are true?
A
The pressure of a fixed amount of an ideal gas is proportional to its temperature only
B
Frequency of collisions increases in proportion to the square root of temperature
C
The value of van der Waals constant '$a$' is smaller for ammonia than for nitrogen
D
If a gas is expanded at constant temperature, the kinetic energy of the molecules decrease

Solution

(B) According to the kinetic theory of gases, the average speed of gas molecules is proportional to $\sqrt{T}$. Since the frequency of collisions is directly proportional to the average speed of the molecules, it follows that the frequency of collisions increases in proportion to the square root of temperature $(\sqrt{T})$.
152
EasyMCQ
According to the kinetic molecular theory of gases, the average kinetic energy of gas molecules:
A
Increases with increase in pressure
B
Decreases with increase in volume
C
Is directly proportional to the absolute temperature
D
Is the same for all gases at the same volume

Solution

(C) The average kinetic energy of gas molecules is given by the formula $KE_{avg} = \frac{3}{2} k_B T$, where $k_B$ is the Boltzmann constant and $T$ is the absolute temperature.
Since $k_B$ is a constant, the average kinetic energy is directly proportional to the absolute temperature $T$.
153
EasyMCQ
Which of the following statements is true about an ideal gas?
A
It shows deviation from Boyle's law and Charles' law.
B
Its molecules are not perfectly elastic.
C
It does not exist in reality.
D
Intermolecular attraction is present in it, hence a collision takes place with loss of kinetic energy.

Solution

(C) $1$. An ideal gas is a theoretical model that obeys gas laws under all conditions of temperature and pressure.
$2$. The kinetic molecular theory assumes that ideal gas molecules have no volume and no intermolecular forces of attraction.
$3$. Since these conditions cannot be met by real gases, an ideal gas does not exist in reality.

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