Predict the major product of the following reaction:

Different possible thermal decomposition pathways for peroxyesters are shown below. Match each pathway from List-$I$ with an appropriate structure from List-$II$ and select the correct answer using the code given below the lists.
List-$I$:
$P$. Pathway $P$
$Q$. Pathway $Q$
$R$. Pathway $R$
$S$. Pathway $S$
List-$II$:
$1$. $C_6H_5CH_2CO_3CH_3$
$2$. $C_6H_5CO_3CH_3$
$3$. $C_6H_5CH_2CO_3C(CH_3)_2CH_2C_6H_5$
$4$. $C_6H_5CO_3C(CH_3)_2C_6H_5$
Codes:
$P \quad Q \quad R \quad S$
$A. 1 \quad 3 \quad 4 \quad 2$
$B. 2 \quad 4 \quad 3 \quad 1$
$C. 4 \quad 1 \quad 2 \quad 3$
$D. 3 \quad 2 \quad 1 \quad 4$

The heterolytic cleavage of a carbon-chlorine bond gives:

Identify the product of the above rearrangement reaction.

Show the heterolytic and homolytic cleavage of $H_3C-Br$.

Which of the following statements is $NOT$ correct for heterolysis?