At $500\,^oC$,cyclopropane isomerizes to propene. This reaction is first order with a rate constant of $6.7 \times 10^{-4}\,s^{-1}$. If the initial concentration of cyclopropane is $0.05\, M$,what will be the molarity of cyclopropane after $30\, min$ (in $, M$)?

If the decomposition reaction $A_{(g)} \longrightarrow B_{(g)}$ follows first-order kinetics,then the graph of the rate of formation of $B$,denoted by $R$,against time $t$ will be:

The following data were obtained during the first order thermal decomposition of $SO_{2}Cl_{2}$ at a constant volume.
$SO_{2}Cl_{2(g)} \to SO_{2(g)} + Cl_{2(g)}$

Experiment	Time $/$ $s$	Total pressure $/$ $atm$
$1$	$0$	$0.5$
$2$	$100$	$0.6$

Calculate the rate of the reaction when total pressure is $0.65 \ atm$.

For a first-order reaction $A \rightarrow \text{product}$, the rate constant is $k = 2 \times 10^{-2} \text{ s}^{-1}$. If the initial concentration of $A$ is $[A]_0 = 1.0 \text{ mol dm}^{-3}$, find the value of $\log \frac{1}{[A]_t}$ after $t = 100 \text{ s}$.

The rate constant for a first order reaction is $7.0 \times 10^{-4} \ s^{-1}$. If initial concentration of the reactant is $0.080 \ M$,what is the half-life of the reaction?

$t_{87.5}$ is the time required for the reaction to undergo $87.5 \%$ completion and $t_{50}$ is the time required for the reaction to undergo $50 \%$ completion. The relation between $t_{87.5}$ and $t_{50}$ for a first order reaction is $t_{87.5} = x \times t_{50}$. The value of $x$ is $......$. (Nearest integer)