$t_{87.5}$ is the time required for the reaction to undergo $87.5 \%$ completion and $t_{50}$ is the time required for the reaction to undergo $50 \%$ completion. The relation between $t_{87.5}$ and $t_{50}$ for a first order reaction is $t_{87.5} = x \times t_{50}$. The value of $x$ is $......$. (Nearest integer)

  • A
    $4$
  • B
    $2$
  • C
    $3$
  • D
    $1$

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In a first-order reaction,the concentration of the reactant decreases from $1.0 \, M$ to $0.25 \, M$ in $20 \, \text{minutes}$. What will be the rate constant of the reaction?

Time required for $90 \%$ completion of a first order reaction is $t$. What is the time required for $99.9 \%$ completion of reaction?

For the first order reaction $2 N_2O_{5(g)} \rightarrow 4 NO_{2(g)} + O_{2(g)}$,which of the following statements are correct?
$A.$ The concentration of the reactant decreases exponentially with time.
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$C.$ The half-life of the reaction depends on the initial concentration of the reactant.
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Given below are two statements:
Statement $I$: The graph of $t_{1/2}$ versus initial concentration $[R]_0$ for a first-order reaction is a horizontal line.
Statement $II$: The graph of $\log \frac{[R]_0}{[R]}$ versus time $t$ for a first-order reaction is a straight line passing through the origin with a slope equal to $\frac{k}{2.303}$.
In the light of the above statements,choose the correct answer from the options given below:

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