Explain the mechanism of dehydration of alcohols with a suitable example.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) $(i)$ Dehydration of alcohols occurs by heating them in the presence of protic acids like concentrated $H_2SO_4$ or $H_3PO_4$ or catalysts like anhydrous $ZnCl_2$ or alumina to form alkenes.
$CH_3CH_2OH \xrightarrow{\text{conc. } H_2SO_4} CH_2=CH_2 + H_2O$
$(ii)$ The dehydration of ethanol proceeds in three steps via a $\beta$-elimination mechanism.
Step-$1$: Protonation of alcohol. The proton $(H^+)$ from the acid attacks the $-OH$ group of the alcohol to form an oxonium ion $(-OH_2^+)$.
Step-$2$: Formation of carbocation. The $C-O$ bond breaks,releasing $H_2O$ and forming a carbocation. This is the slow and rate-determining step.
Step-$3$: Formation of ethene. $A$ $\beta$-proton is eliminated from the carbocation to form ethene. The $H^+$ used in Step-$1$ is released,regenerating the acid catalyst.

Explore More

Similar Questions

An organic compound $X$ on treatment with acidified $K_2Cr_2O_7$ gives a compound $Y$ which reacts with $I_2$ and sodium carbonate to form tri-iodomethane. The compound $X$ is

Difficult
View Solution

$1 \ mol$ of alcohol reacts with $Na$ to produce what weight of hydrogen (in $g$)?

Suggest the reagent for the following conversion:

Which of the following compounds will yield $Propanone$ upon dehydrogenation?

Difficult
View Solution

Among the following compounds,which one can be dehydrated very easily?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo