The $pKa$ of a weak acid $HA$ is $4.5$. The $pOH$ of an aqueous buffer solution in which the acid $HA$ is $50\%$ ionized is:

Which of the following mixtures forms an acidic buffer?

The $pH$ of a buffer solution containing $25 \ mL$ of $1 \ M \ CH_3COONa$ and $25 \ mL$ of $1 \ M \ CH_3COOH$ will be appreciably affected by $5 \ mL$ of

The $pOH$ of a basic buffer (e.g.,$NH_4OH/NH_4Cl$) is $5$. If the concentration of the salt is tripled while the concentration of the base remains constant,find the new $pOH$ value. (Given: $\log 3 = 0.48$)

Assertion : In a titration of weak acid and $NaOH$,the $pH$ at half equivalence point is $pK_a$.
Reason : At half equivalence point,it forms an acidic buffer and the buffer capacity is maximum where $[acid] = [salt]$.

$A$ buffer solution with $pH = 9$ is prepared by mixing $NH_4Cl$ and $NH_4OH$. Calculate the number of moles of $NH_4Cl$ dissolved in $1.0 \, L$ of $1.0 \, M \, NH_4OH$ solution. (Given: $K_b(NH_4OH) = 1.8 \times 10^{-5}$)