Which of the following is not an acidic buffer?

Which of the following cannot act as a buffer solution?

$20 \ mL$ of $0.1 \ M$ $NaOH$ is added to $50 \ mL$ of $0.1 \ M$ acetic acid solution. The $pH$ of the resulting solution is $....... \times 10^{-2}$ (Nearest integer).
Given: $pKa$ $(CH_3COOH)$ $= 4.76$,$\log 2 = 0.30$,$\log 3 = 0.48$.

In which of the following does a buffer solution play an important role?

Calculate the $pH$ of a buffer solution containing $0.027 \ M$ weak acid and $0.054 \ M$ of its salt with a strong base,if the $pK_{a}$ is $4.2$.

What is $[H^{+}]$ in $mol/L$ of a solution that is $0.20\, M$ in $CH_3COONa$ and $0.10\, M$ in $CH_3COOH$? $K_a$ for $CH_3COOH = 1.8 \times 10^{-5}$.