What is $[H^{+}]$ in $mol/L$ of a solution that is $0.20\, M$ in $CH_3COONa$ and $0.10\, M$ in $CH_3COOH$? $K_a$ for $CH_3COOH = 1.8 \times 10^{-5}$.

Which of the following mixtures forms an acidic buffer?

$A$ buffer solution can be prepared from a mixture of

$20 \ mL$ of $0.1 \ M$ acetic acid is mixed with $50 \ mL$ of potassium acetate. $K_a$ of acetic acid $= 1.8 \times 10^{-5}$ at $27^{\circ} C$. Calculate the concentration of potassium acetate if the $pH$ of the mixture is $4.8$. (in $M$)

$A$ solution contains $0.1 \ mol$ of acetic acid and $0.1 \ mol$ of sodium acetate in $500 \ mL$ of solution. If the $pH$ of the solution is $4.74$,find the ionization constant $(K_a)$ of acetic acid.

Assertion $(A)$: The $pH$ of a buffer solution containing equal moles of acetic acid and sodium acetate is $4.8$ ($pK_a$ of acetic acid is $4.8$).
Reason $(R)$: The ionic product of water at $25^{\circ} C$ is $10^{-14} \ mol^2 \ L^{-2}$. The correct answer is