A. Phenyl methanamineB. N,N-DimethylanilineC. | vedclass

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(D) The basic strength of amines depends on the availability of the lone pair on the nitrogen atom.$A$ (Phenyl methanamine,$C_6H_5CH_2NH_2$): The lone

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$A > B > C > D$

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(D) The basic strength of amines depends on the availability of the lone pair on the nitrogen atom.$A$ (Phenyl methanamine,$C_6H_5CH_2NH_2$): The lone pair is not in conjugation with the benzene ring,making it the most basic.$B$ ($N,N$-Dimethylaniline,$C_6H_5N(CH_3)_2$): The lone pair is in conjugation with the benzene ring,but the two methyl groups provide inductive effect $(+I)$,increasing basicity compared to $C$ and $D$.$C$ ($N$-Methylaniline,$C_6H_5NHCH_3$): The lone pair is in conjugation with the benzene ring,and one methyl group provides inductive effect $(+I)$.$D$ (Benzenamine,$C_6H_5NH_2$): The lone pair is in conjugation with the benzene ring,and there is no inductive effect from alkyl groups.Therefore,the order of basic strength is $A > B > C > D$.

$A$. Phenyl methanamine
$B$. $N,N$-Dimethylaniline
$C$. $N$-Methylaniline
$D$. Benzenamine
Choose the correct order of basic nature of the above amines.

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$A$. Phenyl methanamine$B$. $N,N$-Dimethylaniline$C$. $N$-Methylaniline$D$. BenzenamineChoose the correct order of basic nature of the above amines.