$A$ few drops of $KMnO_4$ solution are added to an acidic solution containing an anion. Which of the following,if present,will $NOT$ cause a change in the color of the $KMnO_4$ solution?

Which of the following are redox changes?
$(i)$ Hydrolysis of $XeF_2$
$(ii)$ Thermal decomposition of $Ag_2CO_3$
$(iii)$ Reaction of $Al$ with $NaOH$
$(iv)$ Hydrolysis of $PCl_5$
$(v)$ Reaction of $NaCl$ with conc. $H_2SO_4$
Correct options are:

$50 \ cm^{3}$ of $0.04 \ M \ K_{2}Cr_{2}O_{7}$ in acidic medium oxidizes a sample of $H_{2}S$ gas to sulphur. The volume of $0.03 \ M \ KMnO_{4}$ required to oxidize the same amount of $H_{2}S$ gas to sulphur in acidic medium is: (in $cm^{3}$)

When an acidic solution of $K_2Cr_2O_7$ is added to $Na_2SO_3$,it turns green. Which of the following compounds is formed in this reaction?

$20 \, mL$ of $0.02 \, M \, K_2Cr_2O_7$ solution is used for the titration of $10 \, mL$ of $Fe^{2+}$ solution in the acidic medium. The molarity of $Fe^{2+}$ solution is ........... $\times 10^{-2} \, M$ (Nearest Integer).

Assign $A$,$B$,$C$,$D$ from the given type of reaction.
$MnS(s) + 2HCl(aq) \longrightarrow MnCl_2(aq) + H_2S(g)$