$A$ buffer solution can be prepared by mixing which of the following?

Calculate the $pH$ of the solution in which $0.2 \, M \, NH_{4}Cl$ and $0.1 \, M \, NH_{3}$ are present. The $pK_{b}$ of ammonia solution is $4.75$.

The dissociation constant of $HCN$ is $5 \times 10^{-10}$. The $pH$ of the solution prepared by mixing $1.5 \, mole$ of $HCN$ and $0.15 \, mole$ of $KCN$ in water and making up the total volume to $0.5 \, dm^3$ is (in $.302$)

What would be the $pH$ of a solution obtained by mixing $5 \ g$ of acetic acid and $7.5 \ g$ of sodium acetate and making the volume equal to $500 \ mL$? $(K_a = 1.75 \times 10^{-5}, pK_a = 4.76)$

$A$ weak acid of dissociation constant $10^{-5}$ is being titrated with aqueous $NaOH$ solution. The $pH$ at the point of one-third neutralization of the acid will be:-

The $pH$ of blood is maintained constant by the mechanism of: