Which of the following statements is incorrect?

  • A
    $1^o$ amines give the mustard oil reaction.
  • B
    $1^o$ amines form salts with $H_2PtCl_6$.
  • C
    $1^o$ amines react with sodium to evolve hydrogen gas.
  • D
    $1^o$ amines give alcohol upon hydrolysis.

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Account for the following:
$(i)$ $pK_{b}$ of aniline is more than that of methylamine.
$(ii)$ Ethylamine is soluble in water whereas aniline is not.
$(iii)$ Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
$(iv)$ Although amino group is $o-$ and $p-$ directing in aromatic electrophilic substitution reactions,aniline on nitration gives a substantial amount of $m$-nitroaniline.
$(v)$ Aniline does not undergo Friedel-Crafts reaction.
$(vi)$ Diazonium salts of aromatic amines are more stable than those of aliphatic amines.
$(vii)$ Gabriel phthalimide synthesis is preferred for synthesising primary amines.

What is obtained upon the reduction of $t$-butyl isocyanide?

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The acetylation of ethylamine gives $......$.

The major product formed in the following reaction is:

Aniline reacts with excess $Br_2 / H_2O$ to give the major product.

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