Which of the following compounds does not produce an amine upon hydrolysis?

The compounds $X$ and $Y$ are respectively:

The major product of the following reaction is:

Consider the following sequence of reactions:
Chlorobenzene $\xrightarrow[ii) CO_2, H_3O^{+}]{i) Mg, \text{dry ether}} \text{Benzoic acid}$ $\xrightarrow{NH_3, \Delta} \text{Benzamide (A)}$ $\xrightarrow{Br_2, NaOH} \text{Aniline (B)}$
$11.25 \ mg$ of chlorobenzene will produce $.......... \times 10^{-1} \ mg$ of product $B$.
(Consider the reactions result in complete conversion.)
[Given molar mass of $C, H, O, N$ and $Cl$ as $12, 1, 16, 14$ and $35.5 \ g \ mol^{-1}$ respectively]

Complete the following reactions:
$(i)$ $C_{6}H_{5}NH_{2} + CHCl_{3} +$ alc. $KOH \rightarrow$
$(ii)$ $C_{6}H_{5}N_{2}Cl + H_{3}PO_{2} + H_{2}O \rightarrow$
$(iii)$ $C_{6}H_{5}NH_{2} + H_{2}SO_{4}$ (conc.) $\rightarrow$
$(iv)$ $C_{6}H_{5}N_{2}Cl + C_{2}H_{5}OH \rightarrow$
$(v)$ $C_{6}H_{5}NH_{2} + Br_{2(aq)} \rightarrow$
$(vi)$ $C_{6}H_{5}NH_{2} + (CH_{3}CO)_{2}O \rightarrow$
$(vii)$ $C_{6}H_{5}N_{2}Cl \xrightarrow[(ii) NaNO_{2}/Cu, \Delta ]{(i) HBF_{4}}$

Consider the following sequence of reactions. Assuming that the reaction proceeds to completion, then $137 \ mg$ of $4-$nitrotoluene will produce . . . . . . $mg$ of $B$. (Given molar mass in $g \ mol^{-1}: H = 1, C = 12, N = 14, O = 16, Br = 80$)