What is formed when $1-$propanamine is treated with $NaNO_2$ and $HCl$?

  • A
    $1-$propanol,$2-$propanol
  • B
    Propene
  • C
    $2-$chloropropane,$1-$chloropropane
  • D
    All of the above

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$Ph-NH_2$ $\xrightarrow[Br_2]{HNO_2} A$ $\xrightarrow[Warm]{H_2O} B$
$B$ is

Assertion : Aniline does not undergo Friedel-Crafts reaction.
Reason : $-NH_2$ group of aniline reacts with $AlCl_3$ (Lewis acid) to give acid-base reaction.

Explain the electronic structure of amine compounds with a diagram.

Aniline,when diazotized in cold and then treated with $N,N$-dimethylaniline,gives a coloured product. Its structure would be:

$Benzamide$ $\xrightarrow{Br_2 / NaOH} X$ $\xrightarrow[\text{alc. } KOH]{CHCl_3} Y$
The conversion of $X$ to $Y$ is

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