Which of the following sets represents an example of coordination isomerism in complexes?

  • A
    $[Co(NH_3)_6] [Cr(CN)_6]$ and $[Co(CN)_6] [Cr(NH_3)_6]$
  • B
    $[Cr(H_2O)_5Cl]Cl_2 \cdot H_2O$ and $[Cr(H_2O)_4Cl_2]Cl \cdot 2H_2O$
  • C
    $[Co(NH_3)_5Br]SO_4$ and $[Co(NH_3)_5SO_4]Br$
  • D
    $[Pt(NH_3)_2Cl_2]$ and $[Pt(NH_3)_4] [PtCl_4]$

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Among the following options,select the option in which each complex in Set-$I$ shows geometrical isomerism and the two complexes in Set-$II$ are ionization isomers of each other.
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Which one of the following complexes exhibits chirality?

The spin-only magnetic moment value of $M^{n+}$ ion formed among $Ni$, $Zn$, $Mn$, and $Cu$ that has the least enthalpy of atomisation is $........$ (in nearest integer). Here $n$ is equal to the number of diamagnetic complexes among $K_2[NiCl_4]$, $[Zn(H_2O)_6]Cl_2$, $K_3[Mn(CN)_6]$, and $[Cu(PPh_3)_3I]$.

Arrange the following coordination compounds in the increasing order of magnetic moments. (Atomic numbers: $Mn = 25$; $Fe = 26$)
$(A)$ $[FeF_{6}]^{3-}$
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$(C)$ $[MnCl_{6}]^{3-}$ (high spin)
$(D)$ $[Mn(CN)_{6}]^{3-}$

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