When is methyl tert-butyl ether formed?

  • A
    $(C_2H_5)_3COONa + CH_3Cl$
  • B
    $CH_3ONa + (CH_3)_3CCl$
  • C
    $(CH_3)_3CONa + C_2H_5Cl$
  • D
    $(CH_3)_3CONa + CH_3Cl$

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Dimethyl ether when heated with excess $HI$ gives

Give the major product formed by heating $CH_3-CH_2-CH_2-O-C(CH_3)_2-CH_2-CH_3$ with $HI$.

Match the reactants in Column-$I$ with the major products of their reaction in Column-$II$. Find the correct match for $(I)$ from $(II)$.
Column-$I$ (Reactants)Column-$II$ (Products)
$(A) \ CH_3CH_2CH_2-O-CH_3 + HI \rightarrow$$(i) \ (CH_3)_3C-I + CH_3CH_2OH$
$(B) \ C_6H_5OCH_2CH_3 + HBr \rightarrow$$(ii) \ CH_3CH_2CH_2OH + CH_3I$
$(C) \ (CH_3)_3C-OCH_2CH_3 + HI \rightarrow$$(iii) \ CH_3CH_2I + C_6H_5OH$
$(D) \ C_6H_5OCH_2CH_3 + \text{conc. } H_2SO_4 + \text{conc. } HNO_3 \rightarrow$$(iv) \ p-NO_2-C_6H_4-OCH_2CH_3$

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Which of the following is a suitable method for the preparation of ether via the $Williamson$ synthesis?

Identify the products $R$ and $S$ in the reaction sequence given:
$(CH_3)_3 COH$ $\xrightarrow{Na} P$ $\xrightarrow{CH_3 Br} Q$ $\xrightarrow[\Delta]{HI} R + S$

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