$A$ chemist wants to determine the molecular geometry of the $[CoCl_4]^{2-}$ ion. Which of the following gives the best suggestion for a measurement and for the interpretation of that measurement?

  • A
    Using absorption spectroscopy,measure $\lambda_{max}$ then calculate $\Delta_0$ for octahedral geometry
  • B
    Measure the molecule's magnetic moment and use the result to estimate the number of unpaired spins in the molecule. If this number is low,the geometry is likely to be square planar; otherwise,it is likely to be tetrahedral
  • C
    Measure the molecule's magnetic moment and use the result to estimate the number of unpaired spins in the molecule. If this number is low,the geometry is likely to be tetrahedral; otherwise,it is likely to be square planar
  • D
    Measure the molecule's magnetic moment and use the result to estimate the number of unpaired spins in the molecule. If this number is low,the geometry is likely to be tetrahedral; otherwise,it is likely to be octahedral

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Similar Questions

Given below are two statements:
Statement $I$: $A$ homoleptic octahedral complex,formed using monodentate ligands,will not show stereoisomerism.
Statement $II$: $cis-$ and $trans-$ platin are heteroleptic complexes of $Pd$.
In the light of the above statements,choose the correct answer from the options given below.

Amongst the following ions,which one has the highest paramagnetism?

The magnetic moment of the complexes is zero in:

Which of the following complexes exhibits optical activity?

Which complex among the following has the highest value of spin only magnetic moment?
$[Fe(CN)_6]^{3-}, [Fe(CN)_6]^{4-}, [Ni(CN)_4]^{2-}, [NiCl_4]^{2-}$

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