$A$ first order reaction takes $40 \ min$ for $30 \%$ decomposition. Calculate $t_{1/2}$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) For a first order reaction,the rate constant $k$ is given by:
$k = \frac{2.303}{t} \log \frac{[R]_0}{[R]}$
Given $t = 40 \ min$ and $[R] = [R]_0 - 0.30[R]_0 = 0.70[R]_0$,
$k = \frac{2.303}{40} \log \frac{100}{70} = \frac{2.303}{40} \log(1.4286)$
$k = \frac{2.303}{40} \times 0.1549 = 8.918 \times 10^{-3} \ min^{-1}$
Now,the half-life $t_{1/2}$ is calculated as:
$t_{1/2} = \frac{0.693}{k} = \frac{0.693}{8.918 \times 10^{-3}} \ min$
$t_{1/2} \approx 77.7 \ min$

Explore More

Similar Questions

The first order rate constant for the decomposition of $N_2O_5$ is $6.2 \times 10^{-4} \ s^{-1}$. The half-life period for this decomposition in seconds is:

For any reaction,if we plot a graph between time $t$ and $\log (a - x)$,a straight line is obtained. The order of reaction is

For the first-order gaseous reaction $A_{(g)} \to 2B_{(g)} + C_{(g)}$,the expression for the rate constant $K$ in terms of initial pressure $P_0$ and total pressure $P_t$ at time $t$ is:

The rate constant of the reaction $2 NO_2Cl_{(g)} \longrightarrow 2 NO_{2(g)} + Cl_{2(g)}$ is $4.7672 \text{ minute}^{-1}$. Calculate the half-life of the reaction.

The reaction $2N_2O_5 \,(g) \to 4NO_2 \,(g) + O_2 \,(g)$ follows first order kinetics. The pressure of a vessel containing only $N_2O_5$ was found to increase from $50 \, mmHg$ to $87.5 \, mmHg$ in $30 \, min$. The pressure exerted by the gases after $60 \, min$ will be .......... $mmHg$ (assume temperature remains constant).

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo