The rate constant of the reaction $2 NO_2Cl_{(g)} \longrightarrow 2 NO_{2(g)} + Cl_{2(g)}$ is $4.7672 \text{ minute}^{-1}$. Calculate the half-life of the reaction.

Consider the first-order gas-phase decomposition reaction given below:
$A_{(g)} \longrightarrow B_{(g)} + C_{(g)}$
The initial pressure of the system before the decomposition of $A$ was $P_i$. After time $t$,the total pressure of the system increased by $x \ units$ and became $P_t$. The rate constant $k$ for the reaction is given as:

For a first-order reaction, $20 \%$ of the initial concentration remains after $10 \text{ min}$. What is the rate constant of the reaction (in $\text{ min}^{-1}$)? (Given: $\log_{10}(5) = 0.6989$)

The half-life of a first-order reaction is $2000$ years. If the concentration after $8000$ years is $0.02 \, M$,then the initial concentration was $........... \, M$.

The following data were obtained during the first order thermal decomposition of $SO_{2}Cl_{2}$ at a constant volume.
$SO_{2}Cl_{2(g)} \to SO_{2(g)} + Cl_{2(g)}$

Experiment	Time $/$ $s$	Total pressure $/$ $atm$
$1$	$0$	$0.5$
$2$	$100$	$0.6$

Calculate the rate of the reaction when total pressure is $0.65 \ atm$.

$A$ reaction has a rate constant $k = 2.4 \times 10^{-4} \ s^{-1}$. Find the ratio of $t_{99.9}$ to $t_{50}$.