$A$ plot of $\ln K$ against $\frac{1}{T}$ ($x$-axis) is expected to be a straight line,with intercept on $Y$-axis equal to

  • A
    $\frac{\Delta S^{\circ}}{2.303R}$
  • B
    $\frac{\Delta S^{\circ}}{R}$
  • C
    $-\frac{\Delta S^{\circ}}{R}$
  • D
    $R \times \Delta S^{\circ}$

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$A$ plot of $\ln \ K$ against $\frac{1}{T}$ (abscissa) is expected to be a straight line with an intercept on the ordinate axis equal to:

In a one-litre flask,$6$ moles of $A$ undergoes the reaction $A_{(g)} \rightleftharpoons P_{(g)}$. The progress of product formation at two temperatures (in Kelvin),$T_1$ and $T_2$,is shown in the figure:
If $T_1=2 T_2$ and $(\Delta G_2^{\Theta}-\Delta G_1^{\Theta})=R T_2 \ln x$,then the value of $x$ is. . . . .
$[\Delta G_1^{\Theta}$ and $\Delta G_2^{\Theta}$ are standard Gibb's free energy change for the reaction at temperatures $T_1$ and $T_2$,respectively.]

For the reaction $XCO_{3(s)} \rightleftharpoons XO_{(s)} + CO_{2(g)},$ $K_p = 1.642 \text{ atm}$ at $727^{\circ}C.$ If $4 \text{ moles}$ of $XCO_{3(s)}$ were placed into a $50 \text{ L}$ container and heated to $727^{\circ}C,$ what mole percent of the $XCO_3$ remains unreacted at equilibrium?

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The surface of copper gets tarnished by the formation of copper oxide. $N_2$ gas was passed to prevent the oxide formation during heating of copper at $1250 \ K$. However,the $N_2$ gas contains $1 \ \text{mole}\%$ of water vapour as impurity. The water vapour oxidises copper as per the reaction given below:
$2 Cu_{(s)} + H_2O_{(g)} \longrightarrow Cu_2O_{(s)} + H_{2(g)}$
$p_{H_2}$ is the minimum partial pressure of $H_2$ (in $\text{bar}$) needed to prevent the oxidation at $1250 \ K$. The value of $\ln(p_{H_2})$ is . . . . .
(Given: total pressure $= 1 \ \text{bar}$,$R = 8 \ J \ K^{-1} \ mol^{-1}$,$\ln(10) = 2.3$. $Cu_{(s)}$ and $Cu_2O_{(s)}$ are mutually immiscible.
At $1250 \ K$: $2 Cu_{(s)} + 1/2 O_{2(g)} \longrightarrow Cu_2O_{(s)}; \Delta G^\theta = -78,000 \ J \ mol^{-1}$
$H_{2(g)} + 1/2 O_{2(g)} \longrightarrow H_2O_{(g)}; \Delta G^\theta = -1,78,000 \ J \ mol^{-1}$)

For the reaction $2A_{(g)} + B_{(g)} \rightleftharpoons 3C_{(g)} + D_{(g)}$,two moles each of $A$ and $B$ were taken into a $1 \ L$ flask. Which of the following must always be true when the system attains equilibrium?

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