$A$ uniform rod $AB$ of length $l$ and mass $m$ is free to rotate about point $A$. The rod is released from rest in the horizontal position. Given that the moment of inertia of the rod about $A$ is $\frac{ml^2}{3}$,the initial angular acceleration of the rod will be:

For the electrochemical cell, $Mg ( s )\left| Mg ^{2+}( aq , 1 M ) \| Cu ^{2+}( aq , 1 M )\right| Cu ( s )$ the standard emf of the cell is $2.70 V$ at $300 K$. When the concentration of $Mg ^{2+}$ is changed to $x M$, the cell potential changes to $2.67 V$ at $300 K$. The value of $x$ is.

(given, $\frac{ F }{ R }=11500 K V ^{-1}$, where $F$ is the Faraday constant and $R$ is the gas constant, The value of $\ln (10)=2.30$ )