Among the isomeric amines,select the one with | vedclass

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(C) The boiling point of amines depends on the extent of intermolecular hydrogen bonding. Primary $(1^{\circ})$ and secondary $(2^{\circ})$ amines can

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$1-$methylpiperidine

Vedclass · Answer

(C) The boiling point of amines depends on the extent of intermolecular hydrogen bonding. Primary $(1^{\circ})$ and secondary $(2^{\circ})$ amines can form intermolecular hydrogen bonds due to the presence of $N-H$ bonds,which leads to higher boiling points. Tertiary $(3^{\circ})$ amines do not have any $N-H$ bonds and therefore cannot participate in intermolecular hydrogen bonding. Among the given options,$1$-methylpiperidine is a tertiary amine,while the others are primary or secondary amines. Thus,$1$-methylpiperidine has the lowest boiling point.

Column-$I$	Column-$II$
$A$. Benzenesulphonyl chloride	$1$. Zwitter ion
$B$. Sulphanilic acid	$2$. Hinsberg reagent
$C$. Alkyl diazonium salts	$3$. Dyes
$D$. Aryl diazonium salts	$4$. Conversion to alcohols

Among the isomeric amines,select the one with the lowest boiling point.

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Match the compounds given in Column-$I$ with the items given in Column-$II$.

Column-$I$ Column-$II$

$A$. Benzenesulphonyl chloride $1$. Zwitter ion

$B$. Sulphanilic acid $2$. Hinsberg reagent

$C$. Alkyl diazonium salts $3$. Dyes

$D$. Aryl diazonium salts $4$. Conversion to alcohols

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