An aqueous solution of $CoCl_2$ on addition of excess of concentrated $HCl$ turns blue due to the formation of:

Copper sulphate dissolves in excess of $KCN$ to give

The stability constants for complexes formed by a metal ion $(M^{2+})$ with ligands $NH_3$,$CN^-$,$H_2O$,and $en$ are $10^{11}$,$10^{27}$,$10^{15}$,and $10^8$ respectively. Based on these values,which of the following is correct?

The $IR$ stretching frequencies of free $CO$ and $CO$ in $[V(CO)_6]^-$,$[Cr(CO)_6]$ and $[Mn(CO)_6]^+$ are $2143 \, cm^{-1}$,$1860 \, cm^{-1}$,$2000 \, cm^{-1}$ and $2090 \, cm^{-1}$,respectively. Then the correct statement about metal carbonyls is:

The solubility of $AgCl$ in $NH_4OH$ is due to the formation of:

Discuss the stability of coordination compounds.