(D) The process is an irreversible adiabatic expansion against an external pressure (due to the mass $m$).Since the vessel is thermally insulated,the

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(D) The process is an irreversible adiabatic expansion against an external pressure (due to the mass $m$).Since the vessel is thermally insulated,the heat exchange $q = 0$.For an adiabatic process,the first law of thermodynamics states $\Delta U = q + w$. Since $q = 0$,$\Delta U = w$.In an expansion,the gas does work on the surroundings,so $w Since $\Delta U = n C_{vm} \Delta T$,a decrease in internal energy results in a decrease in temperature,so $T_2 Therefore,none of the given options ($q > 0$,$T_1 V_1^{\gamma - 1} = T_2 V_2^{\gamma - 1}$,$T_1 = T_2$) are correct.

Class 11 Chemistry Thermodynamics Mix Examples-Thermodynamics and Thermochemistry

Difficult

An ideal gas in a thermally insulated vessel at internal pressure $P_1$,volume $V_1$,and absolute temperature $T_1$ expands irreversibly as shown in the following diagram. The final pressure,volume,and absolute temperature of the gas are $P_2$,$V_2$,and $T_2$ respectively. Which is the correct statement for the expansion?

A
$q > 0$
B
$T_1 V_1^{\gamma - 1} = T_2 V_2^{\gamma - 1}$
C
$T_1 = T_2$
D
None of these

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Mix Examples-Thermodynamics and Thermochemistry

Assertion $(A)$: If heat of combustion of $C_2H_6$ is $X \ kJ \ mol^{-1}$,heat liberated on combustion of $150 \ g$ of $C_2H_6$ is $5X \ kJ$.
Reason $(R)$: Enthalpy is an extensive property.

MediumAP EAMCET 2017

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Total enthalpy change for freezing of $1 \ mol$ of water at $10^{\circ} C$ to ice at $-10^{\circ} C$ is $..........$ (Given : $\Delta_{fus} H = x \ kJ / mol$,$C_{p}[H_2O_{(l)}] = y \ J \ mol^{-1} \ K^{-1}$,$C_{p}[H_2O_{(s)}] = z \ J \ mol^{-1} \ K^{-1}$)

DifficultJEE MAIN 2025

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$6 \ g$ of graphite is burnt in a bomb calorimeter at $25^{\circ} C$ and $1 \ atm$ pressure. The temperature of water increased from $25^{\circ} C$ to $31^{\circ} C$. If $\Delta H$ of this reaction is $-248 \ kJ \ mol^{-1}$,find out $C_V$ (in $kJ \ K^{-1}$) of the bomb calorimeter.

MediumAP EAMCET 2019

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One mole of an ideal gas at $900 \ K$ undergoes two reversible processes,$I$ followed by $II$,as shown in the graph. If the work done by the gas in the two processes is the same,the value of $\ln \frac{V_3}{V_2}$ is. . . . . . . . ($U$: internal energy,$S$: entropy,$p$: pressure,$V$: volume,$R$: gas constant). (Given: molar heat capacity at constant volume,$C_{V, m}$ of the gas is $\frac{5}{2} R$)

EasyIIT 2021

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The heat liberated when $1.89 \ g$ of benzoic acid is burnt in a bomb calorimeter at $25^{\circ} C$ increases the temperature of $18.94 \ kg$ of water by $0.632^{\circ} C$. If the specific heat of water at $25^{\circ} C$ is $0.998 \ cal / (g^{\circ} C)$,then find the heat of combustion of benzoic acid.

MediumAP EAMCET 2021

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Assertion $(A)$: If heat of combustion of $C_2H_6$ is $X \ kJ \ mol^{-1}$,heat liberated on combustion of $150 \ g$ of $C_2H_6$ is $5X \ kJ$.Reason $(R)$: Enthalpy is an extensive property.

Total enthalpy change for freezing of $1 \ mol$ of water at $10^{\circ} C$ to ice at $-10^{\circ} C$ is $..........$ (Given : $\Delta_{fus} H = x \ kJ / mol$,$C_{p}[H_2O_{(l)}] = y \ J \ mol^{-1} \ K^{-1}$,$C_{p}[H_2O_{(s)}] = z \ J \ mol^{-1} \ K^{-1}$)

$6 \ g$ of graphite is burnt in a bomb calorimeter at $25^{\circ} C$ and $1 \ atm$ pressure. The temperature of water increased from $25^{\circ} C$ to $31^{\circ} C$. If $\Delta H$ of this reaction is $-248 \ kJ \ mol^{-1}$,find out $C_V$ (in $kJ \ K^{-1}$) of the bomb calorimeter.

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Assertion $(A)$: If heat of combustion of $C_2H_6$ is $X \ kJ \ mol^{-1}$,heat liberated on combustion of $150 \ g$ of $C_2H_6$ is $5X \ kJ$.
Reason $(R)$: Enthalpy is an extensive property.