Arrange the following compounds in their decreasing order of reactivity towards nucleophilic addition reaction: $CH_3COCH_3$,$CH_3COC_2H_5$,$CH_3CHO$.

  • A
    $CH_3CHO > CH_3COCH_3 > CH_3COC_2H_5$
  • B
    $CH_3COCH_3 > CH_3CHO > CH_3COC_2H_5$
  • C
    $CH_3COC_2H_5 > CH_3COCH_3 > CH_3CHO$
  • D
    $CH_3CHO > CH_3COC_2H_5 > CH_3COCH_3$

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Columns $1$,$2$,and $3$ contain starting materials,reaction conditions,and type of reactions,respectively.
$Column-1$ $Column-2$ $Column-3$
$(I)$ Toluene $(i)$ $NaOH / Br_2$ $(P)$ Condensation
$(II)$ Acetophenone $(ii)$ $Br_2 / h\nu$ $(Q)$ Carboxylation
$(III)$ Benzaldehyde $(iii)$ $(CH_3CO)_2O / CH_3COOK$ $(R)$ Substitution
$(IV)$ Phenol $(iv)$ $NaOH / CO_2$ $(S)$ Haloform

$(1)$ For the synthesis of benzoic acid,the only $CORRECT$ combination is
$[A] (III) (iv) (R)$ $[B] (IV) (ii) (P)$ $[C] (I) (iv) (Q)$ $[D] (II) (i) (S)$
$(2)$ The only $CORRECT$ combination in which the reaction proceeds through radical mechanism is
$[A] (I) (ii) (R)$ $[B] (II) (iii) (R)$ $[C] (III) (ii) (P)$ $[D] (IV) (i) (Q)$
$(3)$ The only $CORRECT$ combination that gives two different carboxylic acids is
$[A] (IV) (iii) (Q)$ $[B] (III) (iii) (P)$ $[C] (II) (iv) (R)$ $[D] (I) (i) (S)$

An ester $(A)$ with molecular formula $C_9H_{10}O_2$ was treated with excess of $CH_3MgBr$ and the complex so formed was treated with $H_2SO_4$ to give an olefin $(B)$. Ozonolysis of $(B)$ gave a ketone with molecular formula $C_8H_8O$ which shows positive iodoform test. The structure of $(A)$ is

Explain the different oxidation reactions of aldehydes and ketones.

The major product formed in the following reaction is:

The compound that does not undergo haloform reaction is

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