(D) The Assertion is false because aryl halides do not undergo nucleophilic substitution reactions under ordinary conditions. This is due to the reson

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If both the Assertion and Reason are incorrect.

(D) The Assertion is false because aryl halides do not undergo nucleophilic substitution reactions under ordinary conditions. This is due to the resonance effect,which gives the $C-Cl$ bond partial double bond character,making it shorter and stronger,and thus difficult to replace by nucleophiles.The Reason is also false because $S_{N}2$ reactions proceed with inversion of configuration,not retention.

Class 12 Chemistry Haloalkanes and Haloarenes Properties of Haloarenes

Medium

Assertion : $S_{N}2$ reaction of an optically active aryl halide with an aqueous solution of $KOH$ always gives an alcohol with opposite sign of rotation.
Reason : $S_{N}2$ reactions always proceed with retention of configuration.

AIIMS 2013 All AIIMS

AIIMS 2017 All AIIMS

A
If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
B
If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
C
If the Assertion is correct but Reason is incorrect.
D
If both the Assertion and Reason are incorrect.