Chlorobenzene on heating with concentrated $HNO_3$ in the presence of concentrated $H_2SO_4$ gives:
- A$1-$chloro$-2,4-$dinitrobenzene
- B$2-$chloronitrobenzene and $4-$chloronitrobenzene
- C$1-$chloro$-4-$nitrobenzene
- D$2,4,6-$trinitrochlorobenzene
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Match the reactants in Column-$I$ with their products in Column-$II$.Column-$I$ (Reactants) Column-$II$ (Products) $(A)$ $p$-Nitrochlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 443 \ K}$ $(i)$ Phenol $(B)$ Chlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 623 \ K, 300 \ atm}$ $(ii)$ $2,4,6$-Trinitrophenol $(C)$ $2,4$-Dinitrochlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 368 \ K}$ $(iii)$ $2,4$-Dinitrophenol $(D)$ $2,4,6$-Trinitrochlorobenzene $\xrightarrow{Warm \ H_2O}$ $(iv)$ $p$-Nitrophenol
| Column-$I$ (Reactants) | Column-$II$ (Products) |
|---|---|
| $(A)$ $p$-Nitrochlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 443 \ K}$ | $(i)$ Phenol |
| $(B)$ Chlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 623 \ K, 300 \ atm}$ | $(ii)$ $2,4,6$-Trinitrophenol |
| $(C)$ $2,4$-Dinitrochlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 368 \ K}$ | $(iii)$ $2,4$-Dinitrophenol |
| $(D)$ $2,4,6$-Trinitrochlorobenzene $\xrightarrow{Warm \ H_2O}$ | $(iv)$ $p$-Nitrophenol |
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