Compare the stability of the enolate formed from $A$ (cyclohexane$-1,3-$dione) and $B$ (cyclohexane$-1,4-$dione).
Which of the following statements is true?

  • A
    $A$ is more stable than $B$
  • B
    $A$ and $B$ have the same stability
  • C
    $B$ is more stable than $A$
  • D
    No comparison of stability can be made

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Aldol condensation is a popular and classical method to prepare $\alpha, \beta-$unsaturated carbonyl compounds. This reaction can be both intermolecular and intramolecular. Predict which one of the following is not a product of intramolecular aldol condensation?

Match the reactants in Column-$I$ with the major products in Column-$II$.
Column-$I$ (Reactants)Column-$II$ (Products)
$(A)$ $HCHO + \text{Cyclohexyl-MgBr} \rightarrow X \xrightarrow{H_2O} Y$$(i)$ $\text{Benzenesulfonic acid}$
$(B)$ $\text{2-oxocyclohexylacetate} \xrightarrow{NaBH_4}$$(ii)$ $\text{Cyclohexylmethanol}$
$(C)$ $HCHO + CH_3-CH_2-CH(CH_3)-CH_2-MgBr \rightarrow X \xrightarrow{H_2O} Y$$(iii)$ $\text{2-(2-hydroxycyclohexyl)acetate}$
$(D)$ $\text{Benzene} + \text{Oleum}$$(iv)$ $Y = \text{3-methylpentan-1-ol}$

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