Consider the following complexes:
$(a) \ Na_2[Fe(CN)_5NO]$
$(b) \ [Fe(H_2O)_5NO]SO_4$
$(c) \ K_4[Fe(CN)_6]$
Which of the following statements is wrong?

  • A
    $(a)$ is used in the detection of $S^{2-}$ ions.
  • B
    The complex part of each compound is octahedral.
  • C
    $(c)$ is used in the detection of $Fe^{3+}$ ions.
  • D
    The oxidation state $(O.S.)$ of $Fe$ in $(a)$ and $(b)$ is $+1$.

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The reaction of aqueous $[Ni(H_2O)_6]^{2+}$ is performed by the addition of a bidentate ligand ethane-$1,2$-diamine $(en)$. Match the following:
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$A. 1:1$$I. \text{Pale blue}$
$B. 1:2$$II. \text{Blue/Purple}$
$C. 1:3$$III. \text{Violet}$

The correct match is:

Which of the following complexes is diamagnetic and tetrahedral?

Which of the following compounds is not colored yellow?

The volume (in $mL$) of $0.1 \ M$ $AgNO_3$ required for complete precipitation of chloride ions present in $30 \ mL$ of $0.01 \ M$ solution of $[Cr(H_2O)_5Cl]Cl_2$, as silver chloride is close to

Given below are two statements:
Statement $I$ : Dimethyl glyoxime forms a six-membered covalent chelate when treated with $NiCl_2$ solution in presence of $NH_4OH$.
Statement $II$ : Prussian blue precipitate contains iron both in $(+2)$ and $(+3)$ oxidation states.
In the light of the above statements,choose the most appropriate answer from the options given below:

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