The reaction of aqueous $[Ni(H_2O)_6]^{2+}$ is performed by the addition of a bidentate ligand ethane-$1,2$-diamine $(en)$. Match the following:
$[Ni(H_2O)_6]^{2+} : en$ molar ratioColour of the product
$A. 1:1$$I. \text{Pale blue}$
$B. 1:2$$II. \text{Blue/Purple}$
$C. 1:3$$III. \text{Violet}$

The correct match is:

  • A
    $A-I, B-II, C-III$
  • B
    $A-II, B-III, C-IV$
  • C
    $A-III, B-I, C-II$
  • D
    $A-IV, B-I, C-III$

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Select the incorrect statement.

$A$ mixture $X$ containing $0.02 \, mol$ of $[Co(NH_3)_5SO_4]Br$ and $0.02 \, mol$ of $[Co(NH_3)_5Br]SO_4$ is dissolved in water to make a $2 \, L$ solution.
$1 \, L \, of \, X + \text{Excess of } AgNO_3 \rightarrow Y \, mol \, of \, ppt.$
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Which of the following complexes is diamagnetic and tetrahedral?

The complexes given below show:

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