Consider the following relations for $EMF$ of an electrochemical cell:
$(i)$ $EMF$ of cell = (Oxidation potential of anode) $-$ (Reduction potential of cathode)
$(ii)$ $EMF$ of cell = (Oxidation potential of anode) $+$ (Reduction potential of cathode)
$(iii)$ $EMF$ of cell = (Reduction potential of anode) $+$ (Reduction potential of cathode)
$(iv)$ $EMF$ of cell = (Oxidation potential of anode) $-$ (Oxidation potential of cathode)
Which of the above relations are correct?
$(i)$ $EMF$ of cell = (Oxidation potential of anode) $-$ (Reduction potential of cathode)
$(ii)$ $EMF$ of cell = (Oxidation potential of anode) $+$ (Reduction potential of cathode)
$(iii)$ $EMF$ of cell = (Reduction potential of anode) $+$ (Reduction potential of cathode)
$(iv)$ $EMF$ of cell = (Oxidation potential of anode) $-$ (Oxidation potential of cathode)
Which of the above relations are correct?
- A$(iii)$ and $(i)$
- B$(i)$ and $(ii)$
- C$(iii)$ and $(iv)$
- D$(ii)$ and $(iv)$
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Given are $E^o$ values for some half reactions:
$I_2 + 2e^- \to 2I^{-}; E^o = 0.54 \ V$
$MnO_4^- + 8H^{+} + 5e^- \to Mn^{2+} + 4H_2O; E^o = 1.52 \ V$
$Fe^{3+} + e^- \to Fe^{2+}; E^o = 0.77 \ V$
$Sn^{4+} + 2e^- \to Sn^{2+}; E^o = 0.1 \ V$
The strongest reducant and oxidant respectively are:
$I_2 + 2e^- \to 2I^{-}; E^o = 0.54 \ V$
$MnO_4^- + 8H^{+} + 5e^- \to Mn^{2+} + 4H_2O; E^o = 1.52 \ V$
$Fe^{3+} + e^- \to Fe^{2+}; E^o = 0.77 \ V$
$Sn^{4+} + 2e^- \to Sn^{2+}; E^o = 0.1 \ V$
The strongest reducant and oxidant respectively are:
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View SolutionThe standard electrode potentials $(E^o)$ for $OCl^{-}/Cl^{-}$ and $\frac{1}{2}Cl_2/Cl^{-}$ are $0.94 \ V$ and $+1.36 \ V$ respectively,the $E^o$ value for $OCl^{-}/\frac{1}{2}Cl_2$ will be ........... $V$.
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View SolutionAssertion : $Cu^{2+}$ ions get reduced more easily than $H^{+}$ ions.
Reason : Standard electrode potential of copper is $0.34 \ V$.
Reason : Standard electrode potential of copper is $0.34 \ V$.
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The $E^o$ for the reduction of $NO_3^-$ ion in aqueous solution is $+0.96 \, V$. The $E^o$ values for several metal ions are given below:
$V^{2+}_{(aq)} + 2e^{-} \rightarrow V, \, E^o = -1.19 \, V;$
$Fe^{3+}_{(aq)} + 3e^{-} \rightarrow Fe, \, E^o = -0.04 \, V;$
$Au^{3+}_{(aq)} + 3e^{-} \rightarrow Au, \, E^o = +1.40 \, V;$
$Hg^{2+}_{(aq)} + 2e^{-} \rightarrow Hg, \, E^o = +0.86 \, V$
Which of the following pairs of metals is $NOT$ oxidized by $NO_3^-$ in aqueous solution?
$V^{2+}_{(aq)} + 2e^{-} \rightarrow V, \, E^o = -1.19 \, V;$
$Fe^{3+}_{(aq)} + 3e^{-} \rightarrow Fe, \, E^o = -0.04 \, V;$
$Au^{3+}_{(aq)} + 3e^{-} \rightarrow Au, \, E^o = +1.40 \, V;$
$Hg^{2+}_{(aq)} + 2e^{-} \rightarrow Hg, \, E^o = +0.86 \, V$
Which of the following pairs of metals is $NOT$ oxidized by $NO_3^-$ in aqueous solution?
Difficult
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