Equimolar solutions of the following were prepared in water separately. Which one of the solutions will record the highest $pH$?

Consider a reaction $A+R \rightarrow$ Product. The rate of this reaction is measured to be $k[A][R]$. At the start of the reaction, the concentration of $R,[R]_0$, is $10-$times the concentration of $A,[A]_0$. The reaction can be considered to be a pseudo first order reaction with assumption that $k[R]=k^{\prime}$ is constant. Due to this assumption, the relative error $(in \%)$ in the rate when this reaction is $40 \%$ complete, is $....$
$[ k$ and $k^{\prime}$ represent corresponding rate constants$]$

If $A = \begin{bmatrix} 1 & 0 & 1 \\ 2 & 1 & 0 \\ 3 & 2 & 1 \end{bmatrix}$,then $\det(A)$ is equal to

The pair of straight lines is represented by the equation $3dx^2 - 5xy + (d^2 - 2)y^2 = 0$. If the lines are perpendicular to each other,for how many values of $d$ will this condition be satisfied?

The gold numbers of $A$,$B$,$C$,and $D$ are $0.04$,$0.002$,$10$,and $25$ respectively. The protective power of $A$,$B$,$C$,and $D$ are in the order:

Which one of the following ions has the same number of unpaired electrons as those present in $V^{3+}$ ion?