For the ideal gas reaction,$X + Y \rightleftharpoons Z$,a mixture with $n_{X} = 1 \, mol$,$n_{Y} = 3 \, mol$ and $n_{Z} = 2 \, mol$ is at equilibrium at $300 \, K$ and $1 \, bar$. If the pressure is isothermally increased to $2 \, bar$,the number of moles of $X$ in the new equilibrium is closest to $......$

Calculate $\Delta G^o$ (in $kcal/mole$) for the decomposition of $Cl_{2(g)} \rightleftharpoons 2Cl_{(g)}$,if chlorine molecules are $50\%$ dissociated at $1000 \ K$ at a pressure of $15 \ atm$ at equilibrium $(\ln \ 20 = 2.99)$.

At $473 \ K$, equilibrium constant $K_{c}$ for decomposition of phosphorus pentachloride, $PCl_{5}$, is $8.3 \times 10^{-3}$. If decomposition is depicted as,
$PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)}, \Delta_{r}H^{\Theta} = 124.0 \ kJ \ mol^{-1}$
$(a)$ Write an expression for $K_{c}$ for the reaction.
$(b)$ What is the value of $K_{c}$ for the reverse reaction at the same temperature?
$(c)$ What would be the effect on $K_{c}$ if $(i)$ more $PCl_{5}$ is added $(ii)$ pressure is increased $(iii)$ the temperature is increased?

For the reaction $PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)}$,at equilibrium,the mole fraction of $PCl_5$ is $0.4$ and the mole fraction of $Cl_2$ is $0.3$. What will be the mole fraction of $PCl_3$?

$N_2O_{4(g)}$ at $300 \ K$ is kept in a closed container under $1 \ atm$. At equilibrium,$20\%$ of $N_2O_{4(g)}$ is converted to $NO_{2(g)}$.
$N_2O_{4(g)} \rightleftharpoons 2NO_{2(g)}$
Hence,the resultant pressure is: (in $atm$)

Identify the incorrect statement.