For the reaction $2NOBr(g) \rightarrow 2NO(g) + Br_2(g)$, the rate law is $r = k[NOBr]^2$. If the rate constant $k = 1.62 \times 10^{-2} \text{ L mol}^{-1} \text{ s}^{-1}$ and the concentration of $[NOBr] = 2 \times 10^{-3} \text{ mol L}^{-1}$, what is the rate of reaction?

  • A
    $6.48 \times 10^{-8} \text{ mol L}^{-1} \text{ s}^{-1}$
  • B
    $3.24 \times 10^{-8} \text{ mol L}^{-1} \text{ s}^{-1}$
  • C
    $1.62 \times 10^{-8} \text{ mol L}^{-1} \text{ s}^{-1}$
  • D
    $8.10 \times 10^{-8} \text{ mol L}^{-1} \text{ s}^{-1}$

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Which of the following statements is incorrect?

For the reaction $2 N_2O_{5(g)} \longrightarrow 4 NO_{2(g)} + O_{2(g)}$,the rate and rate constant are $1.02 \times 10^{-4} \ mol \ L^{-1} \ s^{-1}$ and $3.4 \times 10^{-5} \ s^{-1}$ respectively. What is the concentration of $N_2O_5$?

Which of the following reactions has an overall order of $1.5$?

Identify the reaction intermediate of the following reaction sequence:
$(i)$ $2 SO_{2(g)} + 2 NO_{2(g)} \rightarrow 2 SO_{3(g)} + 2 NO_{(g)}$
$(ii)$ $2 NO_{(g)} + O_{2(g)} \rightarrow 2 NO_{2(g)}$
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Overall: $2 SO_{2(g)} + O_{2(g)} \rightarrow 2 SO_{3(g)}$

Assuming the reaction $2NO_{(g)} + Cl_{2(g)} \longrightarrow 2NOCl_{(g)}$ occurs in a single elementary step,we can say that

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