For the reaction of one mole of zinc dust with one mole of sulphuric acid in a bomb calorimeter,$\Delta U$ and $w$ correspond to

Identify the correct statements from the following.
$I$. At $0 \ K$,the entropy of pure crystalline materials approaches zero.
$II$. Entropy for the process,$H_2O_{(l)} \longrightarrow H_2O_{(g)}$ decreases.
$III$. Gibbs' energy is a state function.

For an isothermal expansion of $2 \, \text{mol}$ of a gas at $298 \, K$ from $5 \, dm^3$ to $40 \, dm^3$ under constant external pressure,the work done $(W)$ and the reversible work $(W_{rev})$ are,respectively:

Which of the following relations is not correct?

When $1 \ g$ equivalent of a strong acid reacts with a strong base,the heat released is $13.5 \ kcal$. When $1 \ g$ equivalent of $H_2A$ is completely neutralized against a strong base,$13 \ kcal$ is released. When $1 \ g$ equivalent of $B(OH)_2$ is completely neutralized against a strong acid,$10 \ kcal$ of heat is released. Calculate the enthalpy change when $1 \ mole$ of $H_2A$ is completely neutralized by $B(OH)_2$ in $kcal$.

When $2.0 \ g$ of sucrose is oxidized to form $CO_{2(g)}$ and $H_2O(\ell)$,the internal energy changes by $-24 \ kJ$. Calculate the value of $\Delta H$ at $298 \ K$ in $kJ \ mol^{-1}$. (Molar mass of sucrose $= 342 \ g \ mol^{-1}$)