Given below are two statements:
Statement-$I$: For isothermal irreversible change of an ideal gas,$q = -w = P_{\text{ext}} (V_{\text{final}} - V_{\text{initial}})$
Statement-$II$: For adiabatic change,$\Delta U = W_{\text{adiabatic}}$
The correct answer is

  • A
    Both Statement-$I$ and Statement-$II$ are correct
  • B
    Both Statement-$I$ and Statement-$II$ are not correct
  • C
    Statement-$I$ is correct but Statement-$II$ is not correct
  • D
    Statement-$I$ is not correct but Statement-$II$ is correct

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Similar Questions

Match the following items in List-$I$ with their corresponding expressions in List-$II$.
List-$I$List-$II$
$A$. At constant volume the change in internal energy of a system$I$. $W = -2.303 nRT \log \frac{V_f}{V_i}$
$B$. Isothermal irreversible change$II$. $W_{adiabatic} = \Delta U$
$C$. Isothermal reversible change$III$. $q_V = \Delta U$
$D$. Adiabatic change$IV$. $W = -p_{ex} (V_f - V_i)$
$V$. $\Delta U = \Delta H - \Delta nRT$

For a reaction,$X_{2(g)} + Y_{2(g)} \rightleftharpoons 2XY_{(g)}$. If $\Delta G_r^o = 20 \ kJ \ mol^{-1}$ and $\Delta S_r^o = -20 \ J \ K^{-1} \ mol^{-1}$ at $200 \ K$. Calculate $\Delta H_r^o$ at $400 \ K$ (Given $\Delta_r C_P = 20 \ J \ K^{-1} \ mol^{-1}$).

Assertion $(A)$: If heat of combustion of $C_2H_6$ is $X \ kJ \ mol^{-1}$,heat liberated on combustion of $150 \ g$ of $C_2H_6$ is $5X \ kJ$.
Reason $(R)$: Enthalpy is an extensive property.

When $1.0 \ g$ of solid oxalic acid $(H_2C_2O_4)$ is burned in a bomb calorimeter whose heat capacity is $8.75 \ kJ/K$,the temperature increases by $0.312 \ K$. The enthalpy of combustion of oxalic acid at $27 \ ^oC$ is

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The heat of reaction for $C_6H_{12}O_{6(s)} + 6O_{2(g)} \to 6CO_{2(g)} + 6H_2O_{(l)}$ at constant pressure is $-651 \, kcal$ at $17 \, ^oC$. Calculate the heat of reaction at constant volume at $17 \, ^oC$ in $kcal$.

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