Given:
$(i) \, C(\text{graphite}) + O_{2(g)} \to CO_{2(g)}; \Delta_r H^\ominus = x \, kJ \, mol^{-1}$
$(ii) \, C(\text{graphite}) + \frac{1}{2} O_{2(g)} \to CO_{(g)}; \Delta_r H^\ominus = y \, kJ \, mol^{-1}$
$(iii) \, CO_{(g)} + \frac{1}{2} O_{2(g)} \to CO_{2(g)}; \Delta_r H^\ominus = z \, kJ \, mol^{-1}$
Based on the above thermochemical equations,find out which one of the following algebraic relationships is correct?

  • A
    $x = y + z$
  • B
    $z = x + y$
  • C
    $y = 2z - x$
  • D
    $x = y - z$

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Two reactions are given below:
$2 Fe_{(s)} + \frac{3}{2} O_{2_{(g)}} \rightarrow Fe_2 O_{3_{(s)}}, \Delta H^{o} = -822 \ kJ/mol$
$C_{(s)} + \frac{1}{2} O_{2_{(g)}} \rightarrow CO_{(g)}, \Delta H^{o} = -110 \ kJ/mol$
Then,the enthalpy change for the following reaction is:
$3 C_{(s)} + Fe_2 O_{3_{(s)}} \rightarrow 2 Fe_{(s)} + 3 CO_{(g)}$

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The heat of combustion of solid benzoic acid at constant volume is $-321.30 \ kJ$ at $27^{\circ} C$. Its heat of combustion at constant pressure is :

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