The heat of combustion of solid benzoic acid at constant volume is $-321.30 \ kJ$ at $27^{\circ} C$. Its heat of combustion at constant pressure is :

Given the following thermochemical equations:
$(i) \ H_{2(g)} + \frac{1}{2}O_{2(g)} \rightarrow H_2O_{(l)} ; \Delta H = -68.39 \, kcal$
$(ii) \ K_{(s)} + H_2O_{(l)} + aq \rightarrow KOH_{(aq)} + \frac{1}{2}H_{2(g)} ; \Delta H = -48.0 \, kcal$
$(iii) \ KOH_{(s)} + aq \rightarrow KOH_{(aq)} ; \Delta H = -14.0 \, kcal$
Calculate the heat of formation of $KOH_{(s)}$.

The value of the enthalpy of neutralization of an acid and a base is significant only when $......$

Based on the values of $B.E.$ given,calculate the $\Delta_fH^o$ of $N_2H_4\, (g)$ in $kJ\, mol^{-1}$.
Given : $N-N = 159\, kJ\, mol^{-1};\, H-H = 436\, kJ\, mol^{-1}$
$N \equiv N = 941\, kJ\, mol^{-1};\, N-H = 398\, kJ\, mol^{-1}$

Which of the following reactions satisfies the following conditions?
$(a)$ Heat of combustion reaction
$(b)$ Heat of formation reaction
$(c)$ An exothermic reaction
$(d)$ Not a neutralization reaction

Nitroglycerine $(MW = 227.1)$ detonates according to the following equation:
$2 C_{3}H_{5}(NO_{3})_{3(l)} \longrightarrow 3 N_{2(g)} + \frac{1}{2} O_{2(g)} + 6 CO_{2(g)} + 5 H_{2}O_{(g)}$
The standard molar enthalpies of formation,$\Delta H_{f}^{\circ}$ for all the compounds are given below:
$\Delta H_{f}^{\circ}[C_{3}H_{5}(NO_{3})_{3}] = -364 \, kJ/mol$
$\Delta H_{f}^{\circ}[CO_{2(g)}] = -393.5 \, kJ/mol$
$\Delta H_{f}^{\circ}[H_{2}O_{(g)}] = -241.8 \, kJ/mol$
$\Delta H_{f}^{\circ}[N_{2(g)}] = 0 \, kJ/mol$
$\Delta H_{f}^{\circ}[O_{2(g)}] = 0 \, kJ/mol$
The enthalpy change when $10 \, g$ of nitroglycerine is detonated is $..... \, kJ$.