Homolytic fission of the following alkanes forms free radicals: $CH_3-CH_3$,$CH_3-CH_2-CH_3$,$(CH_3)_2CH-CH_3$,and $CH_3-CH_2-CH(CH_3)_2$. The increasing order of stability of the resulting free radicals is:

  • A
    $CH_3-\dot{C}H_2 < (CH_3)_2\dot{C}H < (CH_3)_2\dot{C}-CH_2CH_3 < (CH_3)_3\dot{C}$
  • B
    $CH_3-\dot{C}H_2 < CH_3-\dot{C}H-CH_3 < (CH_3)_2\dot{C}-CH_2-CH_3 < (CH_3)_3\dot{C}$
  • C
    $CH_3-\dot{C}H_2 < CH_3-\dot{C}H-CH_3 < (CH_3)_3\dot{C} < (CH_3)_2\dot{C}-CH_2CH_3$
  • D
    $(CH_3)_3\dot{C} < (CH_3)_2\dot{C}-CH_2CH_3 < CH_3-\dot{C}H-CH_3 < CH_3-\dot{C}H_2$

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The central carbon atom of a free radical contains

What is the correct order of stability for the following carbocations?

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The correct stability order for the following species is:

Which of the following carbocations is the least stable?

Arrange the following carbocations in increasing order of stability:
$1. \, (CH_3)_2 - \overset{+}{C} - CH_2 - CH_3$
$2. \, (CH_3)_3 - \overset{+}{C}$
$3. \, (CH_3)_2 - \overset{+}{C} H$
$4. \, CH_3 - \overset{+}{C} H_2$
$5. \, \overset{+}{C} H_3$

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