How does the mean free path vary with the number density of a gas?

If $n$ is the number density and $d$ is the diameter of the molecule,then the average distance covered by a molecule between two successive collisions (i.e. mean free path) is represented by :

The value of critical temperature in terms of van der Waals' constants $a$ and $b$ is given by

If the radius of an $O_{2}$ molecule is $40 \; \mathring{A}$,$T = 27^{\circ}C$,and $P = 1 \; \text{atm}$,find the relaxation time.

Two ideal gas thermometers $A$ and $B$ use oxygen and hydrogen respectively. The following observations are made:

Temperature	Pressure thermometer $A$	Pressure thermometer $B$
Triple-point of water	$1.250 \times 10^{5} \; Pa$	$0.200 \times 10^{5} \; Pa$
Normal melting point of sulphur	$1.797 \times 10^{5} \; Pa$	$0.287 \times 10^{5} \; Pa$

$(a)$ What is the absolute temperature of the normal melting point of sulphur as read by thermometers $A$ and $B$?
$(b)$ What do you think is the reason behind the slight difference in answers of thermometers $A$ and $B$? (The thermometers are not faulty). What further procedure is needed in the experiment to reduce the discrepancy between the two readings?

State the differences between an ideal gas and a real gas.