How many $(\sigma)$ and $(\pi)$ bonds are present in the structure of $DDT$ respectively?

Correct statements regarding alkyl halides ($R-X$) among the following are: A. Alcohol being less polar solvent as compared to water, alcoholic $KOH$ favours elimination reaction with $R-X$. B. Order of reactivity towards $S_N1$ mechanism is $C_6H_5-CH_2-Cl > C_6H_5-CHCl-C_6H_5$. C. Non substituted aryl halides exhibit properties similar to alkyl halides. D. Vinyl chloride is an example of haloalkene and allyl chloride is an example of haloalkyne. E. $R-Cl$ can be prepared by reacting $R-OH$ with $SOCl_2$ but $Ar-Cl$ cannot be prepared by reacting $Ar-OH$ with $SOCl_2$. Choose the correct answer from the options given below:

Identify the product in the following reaction:

Which of the following cannot undergo nucleophilic substitution under ordinary conditions?

Write the structure of the major organic product in each of the following reactions:
$(i)$ $CH_3-CH_2-CH_2-Cl + NaI \xrightarrow[\text{heat}]{\text{acetone}}$
$(ii)$ $CH_3-C(CH_3)_2-Br + KOH \xrightarrow[\text{heat}]{\text{ethanol}}$
$(iii)$ $CH_3-CH(Br)-CH_2-CH_3 + NaOH \xrightarrow{\text{water}}$
$(iv)$ $CH_3-CH_2-Br + KCN \xrightarrow{\text{aq. ethanol}}$
$(v)$ $C_6H_5-ONa + C_2H_5-Cl \longrightarrow$
$(vi)$ $CH_3-CH_2-CH_2-OH + SOCl_2 \longrightarrow$
$(vii)$ $CH_3-CH_2-CH=CH_2 + HBr \xrightarrow{\text{peroxide}}$
$(viii)$ $CH_3-CH=C(CH_3)_2 + HBr \longrightarrow$

Match the following lists:

List-$I$	List-$II$
$(A)$ Benzene	$1$. Phosgene
$(B)$ Ethylene	$2$. Silver mirror
$(C)$ Acetaldehyde	$3$. Mustard gas
$(D)$ Chloroform	$4$. $(4n + 2) \pi$ electrons
	$5$. Carbylamine