Identify the reactions in which dichromate acts as an oxidising reagent.
$I$. $Cr_2O_7^{2-} + 6Fe^{2+} + 14H^{+} \longrightarrow 2Cr^{3+} + 6Fe^{3+} + 7H_2O$
$II$. $Cr_2O_7^{2-} + 2OH^{-} \longrightarrow 2CrO_4^{2-} + H_2O$
$III$. $Cr_2O_7^{2-} + 6I^{-} + 14H^{+} \longrightarrow 2Cr^{3+} + 3I_2 + 7H_2O$
$IV$. $Na_2Cr_2O_7 + 2KCl \longrightarrow K_2Cr_2O_7 + 2NaCl$

$FeSO_4 \cdot 7H_2O$ (Green Vitriol) salt on thermal decomposition does not produce

The ionic charges on chromate ion and dichromate ion respectively are:

What are the oxidation states of iron in the minerals hematite and magnetite?

Fusion of $MnO_2$ with $KOH$ in presence of $O_2$ produces a salt $W$. Alkaline solution of $W$ upon electrolytic oxidation yields another salt $X$. The manganese containing ions present in $W$ and $X$,respectively,are $Y$ and $Z$. Correct statement$(s)$ is (are)
$(1)$ $Y$ is diamagnetic in nature while $Z$ is paramagnetic
$(2)$ Both $Y$ and $Z$ are coloured and have tetrahedral shape
$(3)$ In both $Y$ and $Z$,$\pi$-bonding occurs between $p$-orbitals of oxygen and $d$-orbitals of manganese.
$(4)$ In aqueous acidic solution,$Y$ undergoes disproportionation reaction to give $Z$ and $MnO_2$.

Among the following,the compound that is both paramagnetic and coloured is