If the freezing point of an aqueous solution of salt $MX_4$ $(\alpha = 90\%)$ is $-3\ ^oC$,then its boiling point will be ........ $^oC$. (Assume it is $100\%$ ionized at the boiling temperature and $k_f = 1.86\ K\ kg\ mol^{-1}$,$k_b = 0.52\ K\ kg\ mol^{-1}$)

The specific heat of a certain substance is $0.86 \,J \,g^{-1} \,K^{-1}$. Assuming ideal solution behaviour,the energy required (in $J$) to heat $10 \,g$ of $1 \,molal$ of its aqueous solution from $300 \,K$ to $310 \,K$ is closest to $.... \,J$
[Given: Molar mass of the substance $= 58 \,g \,mol^{-1}$; specific heat of water $= 4.2 \,J \,g^{-1} \,K^{-1}$]

Select the correct statement for an ideal solution of a non-volatile solute in a liquid solvent.

Calculate the osmotic pressure in $atm$ at $0\,^oC$ of a $0.18\, m$ aqueous solution of $KCl$ which has a freezing point of $-0.68\,^oC$. Assume the volume of the solution is equal to the volume of pure water. $(K_f = 1.86\,^oC\, m^{-1})$

Evaluate the following statements for their correctness.
$(A)$ The elevation in boiling point temperature of water will be same for $0.1 \ M \ NaCl$ and $0.1 \ M$ urea.
$(B)$ Azeotropic mixtures boil without change in their composition.
$(C)$ Osmosis always takes place from hypertonic to hypotonic solution.
$(D)$ The density of $32 \% \ H_2SO_4$ solution having molarity $4.09 \ M$ is approximately $1.26 \ g \ mL^{-1}$.
$(E)$ $A$ negatively charged sol is obtained when $KI$ solution is added to silver nitrate solution.
Choose the correct answer from the options given below:

On dissolving $0.5 \ g$ of a non-volatile non-ionic solute to $39 \ g$ of benzene,its vapor pressure decreases from $650 \ mm \ Hg$ to $640 \ mm \ Hg$. The depression of freezing point of benzene (in $K$) upon addition of the solute is. . . . .
(Given data : Molar mass and the molal freezing point depression constant of benzene are $78 \ g \ mol^{-1}$ and $5.12 \ K \ kg \ mol^{-1}$,respectively)