If the half-lives of a first-order reaction at $350 \ K$ and $300 \ K$ are $2 \ s$ and $20 \ s$ respectively,the activation energy of the reaction in $kJ \ mol^{-1}$ is:

  • A
    $40.2$
  • B
    $20.1$
  • C
    $60.3$
  • D
    $30.2$

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Similar Questions

Half life of a first order reaction is $900 \ \text{min}$ at $400 \ K$. Find its half life at $300 \ K$. Given: $\frac{E_a}{2.303 \ R} = 1.3056 \times 10^3 \ K$. (in $\text{min}$)

Which of the following is true for a reaction as per collision theory?

Catalyst $A$ reduces the activation energy for a reaction by $10 \ kJ \ mol^{-1}$ at $300 \ K$. The ratio of rate $\frac{k_{T, \text{Catalysed}}}{k_{T, \text{Uncatalysed}}}$ is $e^{x}$. Find the value of $x$ [nearest integer].
[Assume that the pre-exponential factor is same in both the cases.
Given $R = 8.31 \ J \ K^{-1} \ mol^{-1}$]

At $527 \, ^{\circ}C$ temperature,the activation energy is $54.7 \, kJ/mol$. The value of the Arrhenius factor is $4 \times 10^{10}$. The rate constant will be:

The rate constant for the decomposition of $N_{2}O_{5}$ at various temperatures is given below:
$T / ^{\circ}C$$0$$20$$40$$60$$80$
$10^{5} \times k / s^{-1}$$0.0787$$1.70$$25.7$$178$$2140$

Draw a graph between $\ln k$ and $1 / T$ and calculate the values of $A$ and $E_{a}.$ Predict the rate constant at $30^{\circ}C$ and $50^{\circ}C$.

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