In a reaction between $A$ and $B$,the initial rate of reaction $(r_0)$ was measured for different initial concentrations of $A$ and $B$ as given below:
$A / mol \ L^{-1}$ $0.20$ $0.20$ $0.40$
$B / mol \ L^{-1}$ $0.30$ $0.10$ $0.05$
$r_0 / mol \ L^{-1} \ s^{-1}$ $5.07 \times 10^{-5}$ $5.07 \times 10^{-5}$ $1.43 \times 10^{-4}$

What is the order of the reaction with respect to $A$ and $B$?

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(A) Let the order of the reaction with respect to $A$ be $x$ and with respect to $B$ be $y$.
Therefore,the rate law is given by:
$r_0 = k[A]^x[B]^y$
From the given data:
$5.07 \times 10^{-5} = k[0.20]^x[0.30]^y$ $(i)$
$5.07 \times 10^{-5} = k[0.20]^x[0.10]^y$ $(ii)$
$1.43 \times 10^{-4} = k[0.40]^x[0.05]^y$ $(iii)$
Dividing equation $(i)$ by $(ii)$:
$\frac{5.07 \times 10^{-5}}{5.07 \times 10^{-5}} = \frac{k[0.20]^x[0.30]^y}{k[0.20]^x[0.10]^y}$
$1 = (3)^y$
Since $3^0 = 1$,we get $y = 0$.
Now,dividing equation $(iii)$ by $(ii)$ and substituting $y = 0$:
$\frac{1.43 \times 10^{-4}}{5.07 \times 10^{-5}} = \frac{k[0.40]^x[0.05]^0}{k[0.20]^x[0.10]^0}$
$2.82 = (2)^x$
Taking log on both sides:
$\log(2.82) = x \log(2)$
$x = \frac{0.450}{0.301} \approx 1.5$
Hence,the order of the reaction with respect to $A$ is $1.5$ and with respect to $B$ is $0$.

Explore More

Similar Questions

Which of the following statements is false?

Identify the order of the following reaction:
$2H_2O_{2(aq)} \longrightarrow 2H_2O_{(l)} + O_{2(g)}$

For the reaction $A + B \rightarrow$ products,doubling the concentration of $A$ increases the reaction rate by four times,but doubling the concentration of $B$ has no effect on the reaction rate. What is the rate law?

The reaction $2A + B_{2} \rightarrow 2AB$ is an elementary reaction. For a certain quantity of reactants,if the volume of the reaction vessel is reduced by a factor of $3,$ the rate of the reaction increases by a factor of $.....$. (Round off to the Nearest Integer).

By “the overall order of a reaction”,we mean

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo