In basic medium,$CrO_{4}^{2-}$ oxidises $S_{2}O_{3}^{2-}$ to form $SO_{4}^{2-}$ and itself changes into $Cr(OH)_{4}^{-}$. The volume of $0.154 \ M \ CrO_{4}^{2-}$ required to react with $40 \ mL$ of $0.25 \ M \ S_{2}O_{3}^{2-}$ is ........... $mL$ (Rounded-off to the nearest integer).

  • A
    $170$
  • B
    $173$
  • C
    $181$
  • D
    $141$

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$2KMnO_4 + 3H_2SO_4 + 5H_2O_2 \rightarrow K_2SO_4 + 2MnSO_4 + 8H_2O + 5O_2$. Find the normality of $H_2O_2$ solution,if $20 \ mL$ of it is required to react completely with $16 \ mL$ of $0.02 \ M \ KMnO_4$ solution. (Molar mass of $KMnO_4 = 158 \ g \ mol^{-1}$)

$A$ white crystalline salt $[A]$ reacts with dilute $HCl$ to produce a suffocating gas $[B]$ and also forms a yellow precipitate. When gas $[B]$ is passed through acidified potassium dichromate,it turns the solution green,forming $[C]$. Identify $A, B$,and $C$ respectively.

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Assign $A, B, C, D$ from the given type of reaction.
$Ba(NO_3)_2 + Na_2SO_4 \longrightarrow BaSO_4 \downarrow + 2NaNO_3$

To measure the quantity of $MnCl_2$ dissolved in an aqueous solution,it was completely converted to $KMnO_4$ using the reaction,
$MnCl_2 + K_2S_2O_8 + H_2O \longrightarrow KMnO_4 + H_2SO_4 + HCl$ (equation not balanced).
Few drops of concentrated $HCl$ were added to this solution and gently warmed. Further,oxalic acid $(225 \ mg)$ was added in portions till the colour of the permanganate ion disappeared. The quantity of $MnCl_2$ (in $mg$) present in the initial solution is . . . . . . . . . (Atomic weights in $g \ mol^{-1}: Mn = 55, Cl = 35.5$ )

In neutral or faintly alkaline medium,$MnO_4^{-}$ oxidizes $I^{-}$ to iodate. What is the volume (in $L$) of $0.02 \ M \ KMnO_4$ required to completely convert $1 \ L$ of $0.5 \ M \ KI$ solution to iodate in neutral or faintly alkaline medium?

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