In the Carius method,a halogen-containing organic compound is heated with fuming nitric acid in the presence of:

Match column $-I$ and column $-II$ with the correct relation:

Column $-I$	Column $-II$
$(i)$ Dumas method	$(a)$ Absorption of $NH_3$ in $H_2SO_4$
$(ii)$ Kjeldahl's method	$(b)$ $BaCl_2$ by added $BaSO_4$
$(iii)$ Carius method	$(c)$ Mixture of Magnesia
$(iv)$ Estimation of phosphorus	$(d)$ $N_2$

Match Column-$I$ and Column-$II$ with the correct relation:

Column-$I$	Column-$II$
$(i).$ Magnesium pyrophosphate	$(a).$ $I_2O_5$
$(ii).$ Barium sulphate	$(b).$ $AgX$
$(iii).$ Iodide pentoxide	$(c).$ $Mg_2P_2O_7$
$(iv).$ Silver halide	$(d).$ $BaSO_4$

In Dumas' method for estimation of nitrogen,$0.3 \ g$ of an organic compound gave $50 \ mL$ of nitrogen collected at $300 \ K$ temperature and $715 \ mm$ pressure. Calculate the percentage composition of nitrogen in the compound. (Aqueous tension at $300 \ K = 15 \ mm$)

State True or False for the following statements:
$(i)$ The volume of $N_2$ is measured by nitrometer.
$(ii)$ The weight of $N_2$ is measured by nitrometer.
$(iii)$ The weight of $NH_3$ is measured by nitrometer.
$(iv)$ The volume of $NH_3$ is measured by nitrometer.

While estimating the nitrogen present in an organic compound by Kjeldahl's method,the ammonia evolved from $0.25 \ g$ of the compound neutralized $2.5 \ mL$ of $2 \ M \ H_2SO_4$. The percentage of nitrogen present in the organic compound is $......$