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Which among the following is the strongest base?

The major product of the following reaction is:
$CH_3-CH(OH)-CH_2-CH_2-NH_2 \xrightarrow[triethylamine]{ethyl\ formate\ (1\ equiv)}$

$A$ compound with molecular mass $180$ is acylated with $CH_3COCl$ to get a compound with molecular mass $390$. The number of amino groups present per molecule of the former compound is:

The following sequence of reactions on $A$ gives:

Nitrobenzene on reduction using zinc in alkaline medium results in $X$. The number of $\sigma$ and $\pi$ bonds in $X$ is

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